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Aromatic compounds bearing one or more powerful electron-withdrawing substituents as well as a leaving team can occasionally endure nucleophilic substitution in lieu of electrophilic substitution. The normal mechanisms of $mathrm S _ mathrm N two$ and $mathrm S _ mathrm N one$ reactions are impossible due to $s p^ two $ -hybridization at the carbons of a benzene ring, but a system that will involve nucleophilic addition followed by elimination, called $S_ mathrm N mathrm Ar $ (nucleophilic aromatic substitution), is feasible.

Attack by a carbon atom with a carbonyl team would give an Alcoholic beverages and at the same time sort a carbon-to-carbon bond. How can we create a C atom in an alkane nucleophilic? This was obtained by Victor Grignard, who developed the organometallic reagent $mathrm R -mathrm MgBr ,$ with the next reaction in diethyl ether:

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Some vital capabilities of the enzymatic SyAr mechanism are the following. The nucleophile that attacks the chlorinated benzene ring can be a carboxylate anion of the enzyme. If the carboxylate assaults, positively charged teams inside the enzyme stabilize the additional electron density that develops within the thioester carbonyl group from the Meisenheimer intermediate.

In the initial step of the following illustration, addition of a hydroxide ion to $p$ -nitrochlorobenzene provides the carbanion; then elimination of a chloride ion yields the substitution solution since the aromaticity of the ring is recovered.

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